Bicyclo[2.2.2]octane-1, 4-dicarboxylic acid: towards transparent metal–organic frameworks. Issue 23 (23rd May 2017)

• Record Type: Journal Article
• Authors: Llabres-Campaner, P. J.; Pitarch-Jarque, J.; Ballesteros-Garrido, R.; Abarca, B.; Ballesteros, R.; García-España, E.
• Is Part Of: Dalton transactions. Volume 46:Issue 23(2017)
• Page Start: 7397
• Page End: 7402
• Publication Date: 2017-05-23
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt00855d
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The preparation of transparent porous materials can offer a different access towards the study of molecules under solid confined space. Abstract : The preparation of transparent porous materials can offer a different access towards the study of molecules under solid confined space. Metal–organic frameworks represent a unique opportunity due to their tunable pore size, however aromatic linkers present strong absorption and reduce the transparency. Herein, we report the first example of a MOF with bicyclic organic dicarboxylic linkers and its use as a solid solvent.