Mild Hydrosilylation of Amides by Platinum N‐Heterocyclic Carbene Catalysts. Issue 14 (4th April 2014)

• Record Type: Journal Article
• Authors: Pisiewicz, Sabine; Junge, Kathrin; Beller, Matthias
• Is Part Of: European journal of inorganic chemistry. Issue 14(2014)
• Page Start: 2345
• Page End: 2349
• Publication Date: 2014-04-04
• Subjects: Homogeneous catalysis -- Hydrosilylation -- Reduction -- Amides -- Amines -- Platinum; Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.201402083
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract: The platinum‐catalyzed hydrosilylation of amides to afford amines selectively is reported. By using defined platinum/N‐heterocyclic carbene complexes, the reduction of secondary and tertiary amines takes place under mild conditions. Abstract : The selective catalytic hydrosilylation of amides is reported. By using defined platinum/N‐heterocyclic carbene (NHC) complexes, the reduction of secondary and tertiary amines proceeds in good yields under mild conditions.