Chiral Self‐Sorting of trans‐Chelating Chiral Ligands upon Formation of PdII Complexes. Issue 15 (May 2014)

• Record Type: Journal Article
• Authors: Meyer‐Eppler, Georg; Topić, Filip; Schnakenburg, Gregor; Rissanen, Kari; Lützen, Arne
• Is Part Of: European journal of inorganic chemistry. Issue 15(2014)
• Page Start: 2468
• Page End: 2468
• Publication Date: 2014-05
• Subjects: Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.201402316
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract: Invited for the cover of this issue is the group of Arne Lützen at the University of Bonn, Germany. The cover image shows two dissymmetric bis(3‐pyridyl) ligands based on a planar chiral pseudo ‐ortho ‐disubstituted [2.2]paracyclophane scaffold. Upon forming a mononuclear [ML2 ] complex with palladium(II) ions, these ligands act in a trans ‐chelating manner and undergo complete chiral self‐sorting. Abstract : This is a very promising result with regard to the selective self‐assembly of defined aggregates from multicomponent mixtures... Read more about the story behind the cover in the Cover Profile and about the research itself onp. 2495 ff .