Cage Metal Complexes: Synthesis, X‐ray Structure, and Spectral and Redox Behavior of the First Hybrid Iron(II) Clathrochelatoscorpionate and Its Pyrazoloxime‐Armed Macrocyclic Intermediate. Issue 12 (7th February 2013)

• Record Type: Journal Article
• Authors: Varzatskii, Oleg A.; Kats (Menkach), Svitlana V.; Penkova, Larysa V.; Volkov, Sergey V.; Dolganov, Alexander V.; Vologzhanina, Anna V.; Bubnov, Yurii N.; Voloshin, Yan Z.
• Is Part Of: European journal of inorganic chemistry. Issue 12(2013)
• Page Start: 1987
• Page End: 1992
• Publication Date: 2013-02-07
• Subjects: Macrocycles -- Cage compounds -- Cycloaddition -- Clathrochelates -- Ligand reactivity; Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.201201545
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract: Cycloaddition of a new pyrazoloxime to macrocyclic iron(II) bis(α‐benzyldioximate) unexpectedly gave a mixture of the first hybrid clathrochelatoscorpionate and its pyrazoloxime‐armed macrocyclic intermediate, which were characterized by X‐ray crystallography, spectroscopy, and cyclic voltammetry. Abstract : The first hybrid clathrochelatoscorpionate and its pyrazoloxime‐armed macrocyclic intermediate were obtained by cycloaddition of a new pyrazoloxime to macrocyclic iron(II) bis(α‐benzyldioximate) and characterized by X‐ray crystallography, spectroscopy, and cyclic voltammetry.