A Consistent Derivation of the Impedance of a Lithium-Ion Battery Electrode and its Dependency on the State-of-Charge. (20th July 2017)

• Record Type: Journal Article
• Authors: Schönleber, M.; Uhlmann, C.; Braun, P.; Weber, A.; Ivers-Tiffée, E.
• Is Part Of: Electrochimica acta. Volume 243(2017)
• Page Start: 250
• Page End: 259
• Publication Date: 2017-07-20
• Subjects: Impedance -- Lithium-Ion Battery -- Open-Circuit-Voltage -- Charge-Transfer -- Diffusion; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2017.05.009
• Languages: English
• ISSNs: 0013-4686

Abstract

Highlights: A derivation of the impedance model of a Lithium-Ion battery electrode is given. The dependency of all partial impedances on the State-of-Charge is revealed. The lasting disagreement in how to model solid-state diffusion is settled. A solid starting point to derive models of any complexity is provided. The connection between differential capacity and solid-state diffusion is revealed. Abstract: A derivation of the fundamental impedance of a Lithium-Ion battery electrode is given, exemplarily conducted for a solid thin-film electrode. The focus of this derivation is not on developing a model which is able to reproduce the exact behaviour of a given electrode, but rather on deriving its fundamental characteristics from few and intuitive assumptions in a simple and transparent way. It is thus shown, that the fundamental impedance of a solid thin-film electrode consists of an RC-element for charge-transfer, a Finite-Length Warburg element for diffusion in the electrolyte and a Finite-Space Warburg element for diffusion in the solid-state. The use of a Finite-Length Warburg element with a serially connected capacitor for modelling diffusion in the solid-state is thus indicated to be physically questionable. In addition, the theoretically expected behaviour of charge-transfer and solid-state diffusion on the degree of lithiation (State-of-Charge) is derived and discussed.