Reaction of Diazo Compounds with Difluorocarbene: An Efficient Approach towards 1, 1‐Difluoroolefins. (19th November 2015)
- Record Type:
- Journal Article
- Title:
- Reaction of Diazo Compounds with Difluorocarbene: An Efficient Approach towards 1, 1‐Difluoroolefins. (19th November 2015)
- Main Title:
- Reaction of Diazo Compounds with Difluorocarbene: An Efficient Approach towards 1, 1‐Difluoroolefins
- Authors:
- Zhang, Zhikun
Yu, Weizhi
Wu, Chenggui
Wang, Chengpeng
Zhang, Yan
Wang, Jianbo - Abstract:
- Abstract: A transition‐metal‐free difluoromethylenation of diazo compounds that proceeds under mild conditions has been developed and is based on the use of TMSCF2 Br as the difluoromethylene source and tetrabutylammonium bromide (TBAB) as the promoter. The chemoselective formal carbene dimerization reaction is achieved owing to the electronic properties and the relative stability of the difluorocarbene intermediate.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 1(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 1(2016)
- Issue Display:
- Volume 128, Issue 1 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 1
- Issue Sort Value:
- 2016-0128-0001-0000
- Page Start:
- 281
- Page End:
- 285
- Publication Date:
- 2015-11-19
- Subjects:
- Carbene -- Diazoverbindungen -- Difluorcarben -- Fluor -- Hydrazone
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201509711 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 2080.xml