Spin‐State Photoswitching Dynamics of the [(TPA)Fe(TCC)]SbF6 Complex. Issue 5 (11th December 2012)

• Record Type: Journal Article
• Authors: Kaszub, Wawrzyniec; Buron‐Le Cointe, Marylise; Lorenc, Maciej; Boillot, Marie‐Laure; Servol, Marina; Tissot, Antoine; Guérin, Laurent; Cailleau, Hervé; Collet, Eric
• Other Names: Murray Keith S. sponsoringEditor.; Oshio Hiroki sponsoringEditor.; Real Jose Antonio sponsoringEditor.
• Is Part Of: European journal of inorganic chemistry. Issue 5/6(2013)
• Page Start: 992
• Page End: 1000
• Publication Date: 2012-12-11
• Subjects: Spin crossover -- Phase transitions -- Polymorphism -- Laser spectroscopy -- Photocrystallography -- Femto­second spectroscopy -- Non‐equilibrium processes; Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.201201083
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract: We report on the spin state photoswitching dynamics triggered by a femtosecond laser of [(TPA)Fe III (TCC)] + cations in a new salt with SbF6 – anions. Femtosecond optical pump‐probe spectroscopy and picosecond X‐ray diffraction techniques were combined to investigate the different steps of the out‐of‐equilibrium dynamics. The obtained results are very consistent with the ones previously reported for the PF6 – salts. If the ultra‐fast responses of the cations in both salts are similar, the spin conversion due to laser heating is slightly shifted to higher temperature in the SbF6 – salt, as its thermal crossover occurs at higher temperature. Abstract : We use time‐resolved optical spectroscopy and X‐ray diffraction in the femtosecond to millisecond time window to investigate the photoswitching dynamics in the spin‐crossover compound [(TPA)Fe(TCC)]SbF6 . The out‐of‐equilibrium processes are compared with spin‐crossover driven by temperature and pressure.