Allenylidene Complexes Based on Pentacenequinone. Issue 29 (21st August 2013)

• Record Type: Journal Article
• Authors: Strinitz, Frank; Waterloo, Andreas; Tucher, Johannes; Hübner, Eike; Tykwinski, Rik R.; Burzlaff, Nicolai
• Is Part Of: European journal of inorganic chemistry. Issue 29(2013)
• Page Start: 5181
• Page End: 5186
• Publication Date: 2013-08-21
• Subjects: Ruthenium -- Allenes -- Density functional calculations -- Fused ring systems; Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.201300759
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract: Stable ruthenium–allenylidene complexes based on pentacenequinone have been synthesized. The complexes show an electronic absorption in the NIR region that arises from forbidden MLCT transitions, as explained by DFT calculations. The crystal structure reveals promising features for the formation of metal‐influenced organic FETs. Abstract : Stable ruthenium–allenylidene complexes based on pentacenequinone have been synthesized. The depicted complex shows an electronic absorption in the NIR region that arises from forbidden MLCT transitions, as explained by DFT calculations. The crystal structure reveals promising features for the formation of metal‐influenced organic FETs.