Nickel‐Catalyzed α‐Allylation of Aldehydes and Tandem Aldol Condensation/Allylation Reaction with Allylic Alcohols. (29th May 2017)
- Record Type:
- Journal Article
- Title:
- Nickel‐Catalyzed α‐Allylation of Aldehydes and Tandem Aldol Condensation/Allylation Reaction with Allylic Alcohols. (29th May 2017)
- Main Title:
- Nickel‐Catalyzed α‐Allylation of Aldehydes and Tandem Aldol Condensation/Allylation Reaction with Allylic Alcohols
- Authors:
- Bernhard, Yann
Thomson, Brodie
Ferey, Vincent
Sauthier, Mathieu - Abstract:
- Abstract: An additive‐free nickel‐catalyzed α‐allylation of aldehydes with allyl alcohol is reported. The reaction is promoted by 1 mol % of in situ formed nickel complex in methanol, and water is the sole by‐product of the reaction. The experimental conditions allow the conversion of various α‐branched aldehydes and α, β‐unsaturated aldehydes as nucleophiles. The same catalyst and reaction conditions enabled a tandem aldol condensation of aldehyde/α‐allylation reaction.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 26(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 26(2017)
- Issue Display:
- Volume 129, Issue 26 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 26
- Issue Sort Value:
- 2017-0129-0026-0000
- Page Start:
- 7568
- Page End:
- 7572
- Publication Date:
- 2017-05-29
- Subjects:
- Aldehyde -- Allylalkohole -- Allylierungen -- Homogene Katalyse -- Nickel
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201703486 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 782.xml