Electrochemical performance of Ti3C2Tx MXene in aqueous media: towards ultrasensitive H2O2 sensing. (1st May 2017)

• Record Type: Journal Article
• Authors: Lorencova, Lenka; Bertok, Tomas; Dosekova, Erika; Holazova, Alena; Paprckova, Darina; Vikartovska, Alica; Sasinkova, Vlasta; Filip, Jaroslav; Kasak, Peter; Jerigova, Monika; Velic, Dusan; Mahmoud, Khaled A.; Tkac, Jan
• Is Part Of: Electrochimica acta. Volume 235(2017)
• Page Start: 471
• Page End: 479
• Publication Date: 2017-05-01
• Subjects: Ti3C2Tx -- H2O2 sensing -- oxygen reduction reactions -- NADH oxidation; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2017.03.073
• Languages: English
• ISSNs: 0013-4686

Abstract

Graphical abstract: Highlights: electrochemical characterization of MXene and oxidized MXene modified GCE. characterization MXene and oxidized MXene modified GCE by other optical methods. preparation of MXene and oxidized MXene modified GCE for detection of O2, NADH and H2 O2 . proposed mechanism for electrochemical instability of MXene at a positive potential window. construction of an ultrasensitive H2 O2 sensor with LOD of 0.7 nM and a response time of 10 s. Abstract: An extensive characterization of pristine and oxidized Ti3 C2 Tx (T: O, OH, F) MXene showed that exposure of MXene to an anodic potential in the aqueous solution oxidizes the nanomaterial forming TiO2 layer or TiO2 domains with subsequent TiO2 dissolution by F − ions, making the resulting nanomaterial less electrochemically active compared to the pristine Ti3 C2 Tx . The Ti3 C2 Tx could be thus applied for electrochemical reactions in a cathodic potential window i.e. for ultrasensitive detection of H2 O2 down to nM level with a response time of ∼10 s. The manuscript also shows electrochemical behavior of Ti3 C2 Tx modified electrode towards oxidation of NADH and towards oxygen reduction reactions.