A template-free synthesis via alkaline route for Nb2O5/carbon nanotubes composite as pseudo-capacitor material with high-rate performance. (1st May 2017)

• Record Type: Journal Article
• Authors: Luo, Guoming; Li, Heshun; Zhang, Daquan; Gao, Lixin; Lin, Tong
• Is Part Of: Electrochimica acta. Volume 235(2017)
• Page Start: 175
• Page End: 181
• Publication Date: 2017-05-01
• Subjects: Composites -- Solvothermal -- Electrochemical properties -- Energy storage; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2017.03.112
• Languages: English
• ISSNs: 0013-4686

Abstract

Graphical abstract: Highlights: A simple four-step method to prepare T-Nb2 O5 /CNTs composite. The composite is with well-dispersed CNTs in the Nb2 O5 phase. The composite has excellent large-current discharge property. The composite has a high energy storage property at high current density. Abstract: In this paper, we report a facile template-free method to prepare the T-Nb2 O5 /CNTs composite. The addition of ammonia induces the electrostatic interaction between functionalized CNTs and niobic acid colloids during hydrothermal process, resulting in CNTs homogeneously distributed in the T-Nb2 O5 phase. The obtained T-Nb2 O5 /CNTs composite shows high rate Li + storage ability with typical intercalation capacitive behaviour. The presence of well-dispersed CNTs in Nb2 O5 can apparently reduce the limitation from diffusion process and increase the high rate charge-discharge capability. From the galvanostatic tests, a capacity of ∼180 mAh g −1 at 1 A g −1 and ∼130 mAh g −1 at 5 A g −1 is attained.