(Pentamethylcyclopentadienyl)cobalt(III)‐Catalyzed Direct Trifluoromethylthiolation of Arenes via C−H Activation. Issue 11 (15th March 2017)

• Record Type: Journal Article
• Authors: Liu, Xu‐Ge; Li, Qingjiang; Wang, Honggen
• Is Part Of: Advanced synthesis & catalysis. Volume 359:Issue 11(2017)
• Page Start: 1942
• Page End: 1946
• Publication Date: 2017-03-15
• Subjects: C−H activation -- cobalt -- silver -- arene trifluoromethylthiolation; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201700066
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: The direct trifluoromethylthiolation of arenes was realized via (pentamethylcyclopentadienyl)cobalt(III)‐catalyzed C(sp 2 )‐H activation and coupling with AgSCF3 under the assistance of a directing group. The reaction features redox‐neutrality, mild conditions, broad substrate scope, and good functional group tolerance. Preliminary mechanistic studies have been conducted. Abstract :