Synthesis of Fluorinated exo‐Glycals through Modified Julia Olefination. Issue 10 (18th February 2013)

• Record Type: Journal Article
• Authors: Habib, Samuel; Larnaud, Florent; Pfund, Emmanuel; Lequeux, Thierry; Fenet, Bernard; Goekjian, Peter G.; Gueyrard, David
• Is Part Of: European journal of organic chemistry. Issue 10(2013)
• Page Start: 1872
• Page End: 1875
• Publication Date: 2013-02-18
• Subjects: Fluorine -- Enols -- Olefination -- Carbohydrates -- Alkenes; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.201201719
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract: An efficient synthesis of fluorinated enol ethers derived from carbohydrates is reported. A modified Julia olefination reaction of functionalized lactones with fluorine‐substituted sulfones gives the corresponding monofluorinated tri‐ or tetrasubstituted exo ‐glycals. Abstract : An efficient synthesis of fluorinated enol ethers derived from carbohydrates is reported. A modified Julia olefination reaction of functionalized lactones with fluorine‐substituted sulfones gives the corresponding monofluorinated tri‐ or tetrasubstituted exo ‐glycals.