Ion irradiation of pure and amorphous CH4 ice relevant for astrophysical environments. Issue 20 (4th May 2017)

• Record Type: Journal Article
• Authors: Vasconcelos, F. A.; Pilling, S.; Rocha, W. R. M.; Rothard, H.; Boduch, P.; Ding, J. J.
• Is Part Of: Physical chemistry chemical physics. Volume 19:Issue 20(2017)
• Page Start: 12845
• Page End: 12856
• Publication Date: 2017-05-04
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c7cp00883j
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : We reported results for ion irradiation of CH4 ice with implications for abundance of molecular species in icy objects in the outer Solar System. Abstract : This work presents a physicochemical study of frozen amorphous methane (at 16 K) under bombardment by medium-mass ions (15.7 MeV 16 O 5+ ) with implications for icy bodies in the outer Solar System exposed to the action of cosmic rays and energetic particles. The experiment was performed at the Grand Accélérateur National d'Ions Lourds (GANIL) located in Caen, France. The results demonstrate that irradiation of CH4 -containing ices by swift medium mass ions with delivered energy covering both stopping power regimes until its implantation on ice ( i.e. electronic and nuclear) leads to the production of many hydrocarbons, such as C2 H2, C2 H4, C2 H6, and C3 H8 (the most abundant daughter species produced). Values for the effective dissociation cross section of CH4 and the average value for the effective formation cross-sections of its daughter species were about 10 −14 cm 2 and 10 −15 cm 2, respectively. The half-life of methane ice in the presence of swift medium mass ions extrapolated to some outer Solar System environments is estimated to be around 10 6 years. The measured sputtering yield of methane due to incoming swift ions was about 7.30 × 10 5 molecules per impact. Such parameters can be used as models to estimate the amount of CH4 and other molecular species desorbed from the icy surfaces that are constantly being incorporated to the gaseous atmosphere in the vicinity of these outer Solar System bodies due to the presence of energetic particles and cosmic rays.