Green and rapid synthesis of zirconium metal–organic frameworks via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds. Issue 43 (8th May 2017)

• Record Type: Journal Article
• Authors: Huang, Yi-Hao; Lo, Wei-Shang; Kuo, Yun-Wei; Chen, Wen-Jin; Lin, Chia-Her; Shieh, Fa-Kuen
• Is Part Of: Chemical communications. Volume 53:Issue 43(2017)
• Page Start: 5818
• Page End: 5821
• Publication Date: 2017-05-08
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c7cc03105j
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A UiO-66 analog was synthesized in 100 s via water-assisted grinding by the evaluation of linker solubility effects. Abstract : A UiO-66 analog was synthesized in 100 s using water-assisted grinding. The linker solubility suggested that tetrafluorobenzene-1, 4-dicarboxylic acid was the best linker. Zr–metal–organic framework nanocrystals displayed good topologies and hydrophobicities, and high water/thermal stabilities. The less amorphous complex led to higher porosities and pore volumes with a 60 min grinding time.