Solving the 31P{1H} NMR spectrum of (Me3Si)3P7 as B[AC]3 case. (3rd June 2017)

• Record Type: Journal Article
• Authors: Matern, Eberhard; Engelhardt, Michael; Hägele, Gerhard
• Is Part Of: Phosphorus, sulfur, and silicon and the related elements. Volume 192:Number 6(2017)
• Page Start: 727
• Page End: 731
• Publication Date: 2017-06-03
• Subjects: 31P{1H} NMR spectrum -- B[AC]3 spin system -- C3 symmetry -- line shape analysis and iteration -- TOPSPIN -- DAISY; Sulfur compounds -- Periodicals; Organosulfur compounds -- Periodicals; Phosphorus compounds -- Periodicals; Organophosphorus compounds -- Periodicals; Silicon compounds -- Periodicals; Organosilicon compounds -- Periodicals; 546
• DOI: 10.1080/10426507.2017.1287705
• Languages: English
• ISSNs: 1042-6507

Abstract

GRAPHICAL ABSTRACT: ABSTRACT: 31 P NMR chemical shifts and coupling constants of (Me3 Si)3 P7 in solution state reveal C3 symmetry which is consistent with a twisted molecular framework as found in solid state. The 31 P{ 1 H} NMR spectrum was iterated as a B[AC]3 system by automated line shape analysis usingDAISY underTOPSPIN .