Synthesis of Highly Active Sub‐Nanometer Pt@Rh Core–Shell Nanocatalyst via a Photochemical Route: Porous Titania Nanoplates as a Superior Photoactive Support. Issue 16 (2nd February 2017)

• Record Type: Journal Article
• Authors: Zhan, Wen‐Wen; Zhu, Qi‐Long; Dang, Song; Liu, Zheng; Kitta, Mitsunori; Suenaga, Kazutomo; Zheng, Lan‐Sun; Xu, Qiang
• Is Part Of: Small. Volume 13:Issue 16(2017)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2017-02-02
• Subjects: core–shell structures -- heterogeneous catalysis -- photochemical route -- porous titania -- sub‐nanometer particles; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.201603879
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract : Sub‐nanometer Pt@Rh nanoparticles highly dispersed on MIL‐125‐derived porous TiO2 nanoplates are successfully prepared for the first time by a photochemical route, where the porous TiO2 nanoplates with a relatively high specific surface area play a dual role as both effective photoreductant and catalyst support. The resulting Pt@Rh/p‐TiO2 can be utilized as a highly active catalyst.