Design of a three-state switchable chromogenic radical-based moiety and its translation to molecular logic systems. Issue 2 (13th April 2017)

• Record Type: Journal Article
• Authors: Mukherjee, Sanjoy; Boudouris, Bryan W.
• Is Part Of: Molecular Systems Design and Engineering. Volume 2:Issue 2(2017)
• Page Start: 159
• Page End: 164
• Publication Date: 2017-04-13
• Subjects: Chemistry -- Molecular aspects -- Periodicals; Chemical engineering -- Molecular aspects -- Periodicals; Nanotechnology -- Periodicals; 620.5
• DOI: 10.1039/c7me00010c
• Languages: English
• ISSNs: 2058-9689

Abstract

Abstract : The phenylgalvinoxyl moiety can exist in three distinctly different forms in small molecules or in polymers. The distinct electronic structure and optical properties of these three forms is the basis for forming a AND logic function, providing insight into the formation mechanism of the radical polymer. Abstract : Three distinctly different and stable colored states of phenylgalvinoxyl ( i.e., neutral phenolic, radical, and anionic species) small molecule and macromolecular systems are evaluated as a function of the solution pH. A clear halochromic effect is readily observed in the design of the polymer, in a manner that is distinct from the more oft-studied small molecule analogs. This key design paradigm allows the chemical nature of the phenylgalvinoxyl moieties to be comparable to a standard AND logic function, which evolves based upon the structural constitution of the material. Moreover, this crucial change in behavior allows for the revelation that the formation of the radical polymer that bears a galvinoxyl pendant group occurs through base-promoted step-wise oxidation, and this, in turn, provides a critical handle by which to design future radical polymer archetypes and to build molecular logic systems based upon this emerging class of functional materials.