Provenance and geochemical behavior of fluorine in the soils of an endemic fluorosis belt, central Iran. (May 2017)

• Record Type: Journal Article
• Authors: Dehbandi, Reza; Moore, Farid; Keshavarzi, Behnam
• Is Part Of: Journal of African earth sciences. Volume 129(2017)
• Page Start: 56
• Page End: 71
• Publication Date: 2017-05
• Subjects: Fluorine -- Geochemistry -- Provenance -- Iran; Earth sciences -- Africa -- Periodicals; Earth sciences -- Middle East -- Periodicals; Geology -- Africa -- Periodicals; Geology -- Middle East -- Periodicals; Sciences de la terre -- Afrique -- Périodiques; Sciences de la terre -- Moyen-Orient -- Périodiques; Géologie -- Afrique -- Périodiques; Géologie -- Moyen-Orient -- Périodiques; Earth sciences; Geology; Africa; Middle East; Periodicals; Electronic journals; 556.05
• DOI: 10.1016/j.jafrearsci.2016.12.016
• Languages: English
• ISSNs: 1464-343X

Abstract

Abstract: The concentration of fluorine, major, trace and rare earth elements (REEs) were used to estimate the probable sources and provenance of fluorine in the soils of an endemic fluorosis belt in central Iran. Total fluorine (TF) in soils varied from 146 to 406 mg/kg with a mean of 277.5 mg/kg. Calculated enrichment factor (EF) and single factor pollution index (SFPI) revealed that the majority of soil samples were moderately contaminated by fluorine. The very strong positive correlation of TF with weathering indices and soil's fine sized fractions indicated that chemical weathering and alteration of parent rocks/soils are the main controlling factors of fluorine behavior in soils. Fluorine affinity to immobile transition trace elements and REEs suggested the role of heavy minerals as the potential F host phases. Modal mineralogy along with SEM-EDX analysis indicated that apatite, fluorapophyllite, epidote, biotite, muscovite and chlorite, as well as, clay minerals are the main F-bearing minerals in the studied soils. Discriminant, bivariate and ternary diagrams of elemental compositions displayed similar geochemical signature of soils to intermediate-acidic rocks and local shales. Based on the weathering indices, soils were immature and showed a non-steady state weathering trend from upper continental crust (UCC), acidic and intermediate igneous source rocks towards shale composition possibly due to mixing of moderately weathered and un-weathered sources of different primary compositions. Highlights: The geochemical behavior of fluorine in soils have been studied. Chemical weathering is the main controlling factor of fluorine in soils. Soils show similar geochemical characteristics to intermediate and felsic rocks.