Back Cover: A Binary Mixture of Ionic Liquids as a New Approach for an Experimental Diffusion Correction in the Study of Activated Processes (ChemPhysChem 10/2017). Issue 10 (19th May 2017)

• Record Type: Journal Article
• Authors: Berghold, Martin; Bächle, Josua; Landgraf, Stephan; Grampp, Günter
• Is Part Of: Chemphyschem. Volume 18:Issue 10(2017)
• Page Start: 1416
• Page End: 1416
• Publication Date: 2017-05-19
• Subjects: diffusion control -- dynamic viscosity -- electron transfer -- EPR spectroscopy -- ionic liquids; Chemistry, Physical and theoretical -- Periodicals; 541.05
• DOI: 10.1002/cphc.201700458
• Languages: English
• ISSNs: 1439-4235

Abstract

Abstract : The Back Cover picture illustrates the interplay between acceleration of a chemical reaction by the temperature and the deceleration by the viscosity. In ionic liquids the temperature dependence of the reaction is often dominated by the high activation energy of the viscosity of the medium. Our viscosity independent measurements clearly show this effect. More information can be found in the Full Paper by S. Landgraf and co‐workers onpage 1288 in Issue 10, 2017 (DOI:10.1002/cphc.201601347 ).