C3-Selective alkenylation of N-acylindoles with unactivated internal alkynes by cooperative nickel/aluminium catalysis. Issue 32 (6th April 2017)
- Record Type:
- Journal Article
- Title:
- C3-Selective alkenylation of N-acylindoles with unactivated internal alkynes by cooperative nickel/aluminium catalysis. Issue 32 (6th April 2017)
- Main Title:
- C3-Selective alkenylation of N-acylindoles with unactivated internal alkynes by cooperative nickel/aluminium catalysis
- Authors:
- Inoue, Fumiyoshi
Saito, Teruhiko
Semba, Kazuhiko
Nakao, Yoshiaki - Abstract:
- Abstract : Highly regio- and stereoselective alkenylation of N -acylindoles with unactivated internal alkynes has been accomplished by cooperative nickel/aluminium catalysis to afford C3-alkenylated indoles. Abstract : Highly regio- and stereoselective alkenylation of N -acylindoles with unactivated internal alkynes has been accomplished by cooperative nickel/aluminium catalysis to afford C3-alkenylated indoles. Coordination of the acyl moiety to a bulky aluminium-based Lewis acid plays a crucial role in the selective functionalization at the C3-position by electron-rich nickel(0) catalysis.
- Is Part Of:
- Chemical communications. Volume 53:Issue 32(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 32(2017)
- Issue Display:
- Volume 53, Issue 32 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 32
- Issue Sort Value:
- 2017-0053-0032-0000
- Page Start:
- 4497
- Page End:
- 4500
- Publication Date:
- 2017-04-06
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc00852j ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2662.xml