Assembling hierarchical metal–oxygen building units with a semirigid tetracarboxylate ligand into a three-dimensional framework for nitrobenzene sensing. Issue 20 (5th May 2017)

• Record Type: Journal Article
• Authors: Song, Xue-Zhi; Gao, Li-Guo; Wang, Yu-Xiang; Chen, Xiao-Lei; Qiao, Liang; Tan, Zhenquan
• Is Part Of: Dalton transactions. Volume 46:Issue 20(2017)
• Page Start: 6523
• Page End: 6527
• Publication Date: 2017-05-05
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt00888k
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A three-dimensional framework collecting hierarchical metal–oxygen multicluster, macrocyclic, and infinite chain-like building units was fabricated and investigated as efficient luminescent sensor towards nitrobenzene. Abstract : In this study, a dense three-dimensional framework (compound1 ) was elaborately fabricated by the assembly of hierarchical metal–oxygen multicluster structural units, macrocyclic structural units, and infinite chain-like building units with a semirigid tetracarboxylate ligand. The good photoluminescent property endows compound1 with the ability to selectively detect nitrobenzene.