1, 3-N, O-Complexes of late transition metals. Ligands with flexible bonding modes and reaction profiles. (20th April 2017)

• Record Type: Journal Article
• Authors: Drover, Marcus W.; Love, Jennifer A.; Schafer, Laurel L.
• Is Part Of: Chemical Society reviews. Volume 46:Number 10(2017)
• Page Start: 2913
• Page End: 2940
• Publication Date: 2017-04-20
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c6cs00715e
• Languages: English
• ISSNs: 0306-0012

Abstract

Abstract : 1, 3- N, O -Chelating ligands are ubiquitous in nature owing to their occurrence as α-chiral amino acids in metalloproteins. Abstract : 1, 3- N, O -Chelating ligands are ubiquitous in nature owing to their occurrence as α-chiral amino acids in metalloproteins. These structural units also display diverse coordination modes, which lend themselves to applications in catalysis as well as novel fundamental stoichiometric reactivity, including the activation of inert bonds. This review comments on recent developments in N, O -ligated late transition metal complexes with an emphasis on preparation, characterization, and reactivity.