Isolation of a Reactive Cyclopropane Intermediate via a Unique Catalyst‐Free Spontaneous Cyclopropanation Step at 0 °C. Issue 25 (27th January 2017)
- Record Type:
- Journal Article
- Title:
- Isolation of a Reactive Cyclopropane Intermediate via a Unique Catalyst‐Free Spontaneous Cyclopropanation Step at 0 °C. Issue 25 (27th January 2017)
- Main Title:
- Isolation of a Reactive Cyclopropane Intermediate via a Unique Catalyst‐Free Spontaneous Cyclopropanation Step at 0 °C
- Authors:
- Braunschweig, Holger
Dewhurst, Rian D.
Ewing, William C.
Kuntze‐Fechner, Maximilian W.
Schäfer, Marius - Abstract:
- Abstract: A remarkably mild, catalyst‐free cyclopropanation reaction is confirmed by low‐temperature isolation of a fused bicyclic cyclopropane intermediate. This intermediate is one of two that were isolated and fully characterised in a three‐step temperature‐controllable reaction cascade. Abstract : Pretty cold fusion : A remarkably mild, catalyst‐free cyclopropanation reaction is confirmed by low‐temperature isolation of a fused bicyclic cyclopropane intermediate.
- Is Part Of:
- Chemistry. Volume 23:Issue 25(2017)
- Journal:
- Chemistry
- Issue:
- Volume 23:Issue 25(2017)
- Issue Display:
- Volume 23, Issue 25 (2017)
- Year:
- 2017
- Volume:
- 23
- Issue:
- 25
- Issue Sort Value:
- 2017-0023-0025-0000
- Page Start:
- 5953
- Page End:
- 5956
- Publication Date:
- 2017-01-27
- Subjects:
- carbenes -- C−H activation -- cyclopropanation -- cyclopropane -- iminoboranes
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3765 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/chem.201605514 ↗
- Languages:
- English
- ISSNs:
- 0947-6539
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3168.860500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1492.xml