Frontispiece: Local Proton Source in Electrocatalytic CO2 Reduction with [Mn(bpy–R)(CO)3Br] Complexes. Issue 20 (6th April 2017)

• Record Type: Journal Article
• Authors: Franco, Federico; Cometto, Claudio; Nencini, Luca; Barolo, Claudia; Sordello, Fabrizio; Minero, Claudio; Fiedler, Jan; Robert, Marc; Gobetto, Roberto; Nervi, Carlo
• Is Part Of: Chemistry. Volume 23:Issue 20(2017)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2017-04-06
• Subjects: carbon dioxide -- density functional calculations -- electrocatalysis -- electrochemistry -- manganese; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201782063
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract : Mn(bpy)‐type complexes bearing local proton source catalyse the electrochemical reduction of CO2 . Depending on the strength of the Brønsted acid added to the solution, CO or formate are produced. Spectroelectrochemical studies under Ar and CO2 atmospheres show fast solvolysis and the dimer formation is suppressed, providing an atypical reduction mechanism of Mn I catalysts. Spectroscopic evidence of Mn hydride formation supports the existence of different electrocatalytic CO2 reduction pathways. For more information, see the Full Paper by R. Gobetto, C. Nervi et al. onpage 4782 ff.