A 11‐Steps Total Synthesis of Magellanine through a Gold(I)‐Catalyzed Dehydro Diels–Alder Reaction. (12th January 2017)
- Record Type:
- Journal Article
- Title:
- A 11‐Steps Total Synthesis of Magellanine through a Gold(I)‐Catalyzed Dehydro Diels–Alder Reaction. (12th January 2017)
- Main Title:
- A 11‐Steps Total Synthesis of Magellanine through a Gold(I)‐Catalyzed Dehydro Diels–Alder Reaction
- Authors:
- McGee, Philippe
Bétournay, Geneviève
Barabé, Francis
Barriault, Louis - Abstract:
- Abstract: We have developed an innovative strategy for the formation of angular carbocycles via a gold(I)‐catalyzed dehydro Diels–Alder reaction. This transformation provides rapid access to a variety of complex angular cores in excellent diastereoselectivities and high yields. The usefulness of this Au I ‐catalyzed cycloaddition was further demonstrated by accomplishing a 11‐steps total synthesis of (±)‐magellanine.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 22(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 22(2017)
- Issue Display:
- Volume 129, Issue 22 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 22
- Issue Sort Value:
- 2017-0129-0022-0000
- Page Start:
- 6377
- Page End:
- 6380
- Publication Date:
- 2017-01-12
- Subjects:
- Diels-Alder-Reaktion -- Gold -- Homogene Katalyse -- Magellanin -- Totalsynthesen
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201611606 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 2657.xml