Substrate‐Assisted, Transition‐Metal‐Free Diboration of Alkynamides with Mixed Diboron: Regio‐ and Stereoselective Access to trans‐1, 2‐Vinyldiboronates. (29th March 2017)
- Record Type:
- Journal Article
- Title:
- Substrate‐Assisted, Transition‐Metal‐Free Diboration of Alkynamides with Mixed Diboron: Regio‐ and Stereoselective Access to trans‐1, 2‐Vinyldiboronates. (29th March 2017)
- Main Title:
- Substrate‐Assisted, Transition‐Metal‐Free Diboration of Alkynamides with Mixed Diboron: Regio‐ and Stereoselective Access to trans‐1, 2‐Vinyldiboronates
- Authors:
- Verma, Astha
Snead, Russell F.
Dai, Yumin
Slebodnick, Carla
Yang, Yinuo
Yu, Haizhu
Yao, Fu
Santos, Webster L. - Abstract:
- Abstract: A substrate‐assisted diboration of alkynamides using the unsymmetrical pinacolato‐1, 8‐diaminonaphthalenato diboron (pinBBdan) is described. The transition‐metal‐free reaction proceeds in a regio‐ and stereoselective fashion to exclusively afford trans ‐vinyldiboronates in good to excellent yields. Notably, Bdan and Bpin are installed on the α‐ and β‐carbon atoms, respectively.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 18(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 18(2017)
- Issue Display:
- Volume 129, Issue 18 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 18
- Issue Sort Value:
- 2017-0129-0018-0000
- Page Start:
- 5193
- Page End:
- 5197
- Publication Date:
- 2017-03-29
- Subjects:
- Alkene -- Bor -- Chemoselektivität -- Kreuzkupplungen -- Synthesemethoden
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201700946 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 1687.xml