Stereocontrolled C(sp3)–P bond formation with non-activated alkyl halides and tosylates. Issue 40 (8th May 2017)
- Record Type:
- Journal Article
- Title:
- Stereocontrolled C(sp3)–P bond formation with non-activated alkyl halides and tosylates. Issue 40 (8th May 2017)
- Main Title:
- Stereocontrolled C(sp3)–P bond formation with non-activated alkyl halides and tosylates
- Authors:
- Yang, Chu-Ting
Han, Jun
Liu, Jun
Li, Yi
Zhang, Fan
Gu, Mei
Hu, Sheng
Wang, Xiaolin - Abstract:
- Abstract : The current work provides a general approach for making C–P bonds with stereocontrol from chiral secondary alcohols. Abstract : The C(sp 3 )–P bond is formed via the reaction between P–H compounds and non-activated alkyl electrophiles, especially secondary alkyl halides and tosylates. This reaction proceeds via an SN 2 mechanism with inversion of configuration, so it can be used to form C–P bonds with stereocontrol from chiral secondary alcohols.
- Is Part Of:
- RSC advances. Volume 7:Issue 40(2017)
- Journal:
- RSC advances
- Issue:
- Volume 7:Issue 40(2017)
- Issue Display:
- Volume 7, Issue 40 (2017)
- Year:
- 2017
- Volume:
- 7
- Issue:
- 40
- Issue Sort Value:
- 2017-0007-0040-0000
- Page Start:
- 24652
- Page End:
- 24656
- Publication Date:
- 2017-05-08
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/RA ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7ra02766d ↗
- Languages:
- English
- ISSNs:
- 2046-2069
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8036.750300
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1627.xml