Tuning liquid crystalline phase behaviour in columnar crown ethers by sulfur substituents. Issue 5 (14th March 2017)

• Record Type: Journal Article
• Authors: Kirres, Jochen; Schmitt, Katharina; Wurzbach, Iris; Giesselmann, Frank; Ludwigs, Sabine; Ringenberg, Mark; Ruff, Adrian; Baro, Angelika; Laschat, Sabine
• Is Part Of: Organic chemistry frontiers. Volume 4:Issue 5(2017)
• Page Start: 790
• Page End: 803
• Publication Date: 2017-03-14
• Subjects: Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1039/c7qo00077d
• Languages: English
• ISSNs: 2052-4110

Abstract

Abstract : Sulfur-containing side chains in the periphery of o -terphenyl or triphenylene units of crown ethers induce room-temperature columnar mesophases. Abstract : Novel [15]crown-5 and [18]crown-6 o -terphenyls differing in number and position of sulfur in the side chains and their corresponding triphenylene analogues were synthesized via a nucleophilic aromatic displacement of fluoride as the key step. Except for one short chain derivative all other compounds showed enantiotropic columnar mesophases which were studied by DSC, POM and XRD (WAXS, SAXS). The presence of sulfur induced broad room temperature columnar mesophases. This effect was more pronounced for bend [15]crown-5 derivatives than for linear [18]crown-6 derivatives. Redox properties were mostly governed by the triphenylene moieties, showing stepwise oxidation of the individual triphenylene units.