Synthesis of homoazafullerene [C59N(CH2)]R and azahomoazafullerene [C59N(NH)]R. Issue 5 (24th February 2017)

• Record Type: Journal Article
• Authors: Xu, Dan; Li, Yanbang; Lou, Ning; Gan, Liangbing
• Is Part Of: Organic chemistry frontiers. Volume 4:Issue 5(2017)
• Page Start: 750
• Page End: 754
• Publication Date: 2017-02-24
• Subjects: Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1039/c7qo00098g
• Languages: English
• ISSNs: 2052-4110

Abstract

Abstract : The selective insertion of a CH2 or NH group is achieved through the PCl5 induced reaction of a CH2 OH or NHOH group, respectively. Abstract : The selective insertion of a CH2 or NH group at the 5, 6-junction on the C59 N skeleton is achieved through the PCl5 induced reaction of a CH2 OH or NHOH group on the cage to form [C59 N(CH2 )]R or [C59 N(NH)]R, respectively. Spectroscopic data and single crystal X-ray diffraction structure analysis confirmed the 5, 6-open homoazafullerene structure.