Diversification reactions of γ-silyl allenyl esters: selective conversion to all-carbon quaternary centers and γ-allene dicarbinols. Issue 37 (24th April 2017)
- Record Type:
- Journal Article
- Title:
- Diversification reactions of γ-silyl allenyl esters: selective conversion to all-carbon quaternary centers and γ-allene dicarbinols. Issue 37 (24th April 2017)
- Main Title:
- Diversification reactions of γ-silyl allenyl esters: selective conversion to all-carbon quaternary centers and γ-allene dicarbinols
- Authors:
- Jana, Susovan
Roy, Animesh
Lepore, Salvatore D. - Abstract:
- Abstract : Taking advantage of an organosilicon auxiliary, allenes are selectively converted under mild conditions to either all-carbon quaternary centers (including via SN Ar) or allene dicarbinols depending on the electrophile. Abstract : The unique reactivity of γ-silyl allenyl esters is described. Taking advantage of the silyl group as a fluoride acceptor, these allenoates readily underwent addition to a variety of electrophiles to selectively yield products with all-carbon quaternary centers or allenoate dicarbinols. These dicarbinols were subsequently converted to novel highly substituted 6-hydro-2-pyrones.
- Is Part Of:
- Chemical communications. Volume 53:Issue 37(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 37(2017)
- Issue Display:
- Volume 53, Issue 37 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 37
- Issue Sort Value:
- 2017-0053-0037-0000
- Page Start:
- 5125
- Page End:
- 5127
- Publication Date:
- 2017-04-24
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc01708a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 39.xml