Effects of adhesives on the electrochemical performance of monodisperse LiMn0.8Fe0.2PO4/C microspheres as cathode materials for high power lithium-ion batteries. Issue 17 (11th April 2017)

• Record Type: Journal Article
• Authors: Li, Jianlong; Xiang, Mingwu; Wang, Yan; Wu, Jinhua; Zhao, Hang; Liu, Heng
• Is Part Of: Journal of materials chemistry. Volume 5:Issue 17(2017)
• Page Start: 7952
• Page End: 7960
• Publication Date: 2017-04-11
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c7ta00104e
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : A facile co-precipitation approach combined with spray-drying and high-temperature calcinations was developed to synthesize LiMn0.8 Fe0.2 PO4 /C microspheres on a large scale. Abstract : A facile co-precipitation approach combined with spray-drying and high-temperature calcinations was developed to synthesize LiMn0.8 Fe0.2 PO4 /C microspheres on a large scale. With an open porous structure, these microspheres are composed of nanoparticles coated with a carbon layer. The electrochemical performances of a LiMn0.8 Fe0.2 PO4 /C cathode were investigated with a water-soluble adhesive, polyacrylic latex (LA133), and compared with the commercial polyvinylidene difluoride (PVDF). The results show that LA133 makes better distribution between the microspheres and acetylene black with a larger and closer contact and stronger adherence. The testing results show that the LiMn0.8 Fe0.2 PO4 /C demonstrates a reversible capacity of 161 mA h g −1 . The electrodes with the LA133 adhesive attain higher discharge capacities than the electrodes with PVDF at a large current density, and deliver a long cycle life of 500 cycles at 5C with an excellent capacity retention ratio of 70.5% at room temperature. Even at a low temperature of 0 °C, the LiMn0.8 Fe0.2 PO4 /C electrodes with LA133 retain a capacity of 117 mA h g −1 and stability.