A note on the effects of inorganic seed aerosol on the oxidation state of secondary organic aerosol—α‐Pinene ozonolysis. Issue 20 (31st October 2016)

• Record Type: Journal Article
• Authors: Huang, Dan Dan; Zhang, Xuan; Dalleska, Nathan F.; Lignell, Hanna; Coggon, Matthew M.; Chan, Chi‐Ming; Flagan, Richard C.; Seinfeld, John H.; Chan, Chak K.
• Is Part Of: Journal of geophysical research. Volume 121:Issue 20(2016)
• Page Start: 12, 476
• Page End: 12, 483
• Publication Date: 2016-10-31
• Subjects: aerosol oxidation state -- inorganic seed aerosol -- highly oxygenated small carboxylic acids; Atmospheric physics -- Periodicals; Geophysics -- Periodicals; 551.5
• DOI: 10.1002/2016JD025999
• Languages: English
• ISSNs: 2169-897X

Abstract

Abstract: We compare the oxidation state and molecular composition of α ‐pinene‐derived secondary organic aerosol (SOA) by varying the types and surface areas of inorganic seed aerosol that are used to promote the condensation of SOA‐forming vapors. The oxidation state of α ‐pinene SOA is found to increase with inorganic seed surface area, likely a result of enhanced condensation of low‐volatility organic compounds on particles versus deposition on the chamber wall. α ‐Pinene SOA is more highly oxygenated in the presence of sodium nitrate (SN) seed than ammonium sulfate seed. The relative abundance of semivolatile monomers and low‐volatility dimer components that account for more than half of α ‐pinene SOA mass is not significantly affected by the composition of seed aerosol. Enhanced uptake of highly oxidized small carboxylic acids onto SN seed particles is observed, which could potentially explain the observed higher SOA oxidation state in the presence of SN seed aerosol. Overall, our results demonstrate that a combined effect of seed aerosol composition and surface area leads to an increase in the O:C atomic ratio of α ‐pinene SOA by as much as a factor of 2. Key Points: Oxidation state of alpha‐pinene SOA increases with increasing seed surface area Alpha‐pinene SOA is more oxidized in the presence of nitrate‐containing seed aerosol than with ammonium sulfate seed aerosol