Insights into the Scholl Coupling Reaction: A Key Transformation of Relevance to the Synthesis of Graphenes and Related Systems. Issue 13 (30th January 2017)

• Record Type: Journal Article
• Authors: Little, Mark S.; Yeates, Stephen G.; Alwattar, Aula A.; Heard, Kane W. J.; Raftery, James; Edwards, Alyn C.; Parry, Adam. V. S.; Quayle, Peter
• Is Part Of: European journal of organic chemistry. Issue 13(2017)
• Page Start: 1694
• Page End: 1703
• Publication Date: 2017-01-30
• Subjects: Scholl reactions -- Oxidation -- Cross‐coupling -- Dimerization -- Fused‐ring systems; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.201601580
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract : The Scholl‐type reactions of 4, 10‐disubstituted chrysene derivatives proceeded by variegated and unexpected oxidation/coupling pathways. These observations serve as a cautionary note when attempting to employ the Scholl reaction in target‐oriented materials synthesis. Abstract : Scholl coupling reactions proceed by unexpected oxidation/coupling pathways.