Continuous CO2 escape from the hypersaline Dead Sea caused by aragonite precipitation. (15th June 2017)

• Record Type: Journal Article
• Authors: Golan, Rotem; Lazar, Boaz; Wurgaft, Eyal; Lensky, Nadav; Ganor, Jiwchar; Gavrieli, Ittai
• Is Part Of: Geochimica et cosmochimica acta. Volume 207(2017)
• Page Start: 43
• Page End: 56
• Publication Date: 2017-06-15
• Subjects: DSB Dead Sea brine -- DSBd diluted Dead Sea brine, 98% by weight -- TA total alkalinity [mmole quivalent kg−1] -- N.TA normalized total alkalinity [mmole quivalentkg−1] -- DIC dissolved inorganic carbon [mmol kg−1] -- C concentration [mol kg−1] -- CA carbonate alkalinity [mmol equivalent kg−1] -- BA borate alkalinity [mmole quivalent kg−1] -- δ13C (δ13CDIC) 13C isotopic value of DIC [‰ vs. PDBV] -- ρ density [g cm−3] -- σ25 quasi-salinity, at 25°C, σ25= (ρ25− 1) · 1000 [kg m−3] -- FW freshwater -- V volume [m3] -- LMg amount of Mg2+ loss [mol] -- M amount [mol] -- Q discharge [m3 yr−1] -- F flux [mol m−2 yr−1] -- α isotopic fractionation factor -- εi enrichment factor, 1000 · (1 − α), subscript i designates the reaction identity: εCO2 and εarag are the ε-s with respect to CO2 loss from the brine to the atmosphere and from the brine to CaCO3 precipitate, respectively -- SPM suspended particulate matter; Carbonate -- Dead Sea -- Alkalinity -- Carbon cycle -- Aragonite; Geochemistry -- Periodicals; Meteorites -- Periodicals; Géochimie -- Périodiques; Météorites -- Périodiques; Geochemie; Astrochemie; Electronic journals; 551.905
• DOI: 10.1016/j.gca.2017.02.031
• Languages: English
• ISSNs: 0016-7037

Abstract

Abstract: Chemical precipitation of CaCO3 occurs in diverse marine and lacustrine environments. In the hypersaline Ca-chloride lakes that have been occupying the Dead Sea basin since the late Pleistocene, CaCO3 precipitated, mostly as aragonite. The aragonite sediments precipitated mainly during periods of high lake level stands as a result of mixing of bicarbonate-rich freshwater runoff with Dead Sea brine, that is Ca-rich and have high Mg/Ca ratio. During periods of arid conditions with limited freshwater inflow, water level declined, salinity increased and gypsum and halite became the dominant evaporitic minerals to precipitate. The present study investigates the carbon cycle of the Dead Sea under the current limited water and bicarbonate supply to the brine, representing periods of extremely arid conditions. The decrease of inflows to the Dead Sea in recent years stems mainly from diversion of freshwater from the drainage basin and results in dramatic water level decline and massive halite precipitation. During 2013–2014, bi-monthly depth profiles of total alkalinity, dissolved inorganic carbon (DIC) and its isotopic composition (δ 13 C) were conducted in the Dead Sea, from surface down to the bottom of the lake (290 m). Mass balance calculations conducted for the period 1993–2013 show that while inventories of conservative ions such as Mg 2+ remained constant, the net DIC inventory of the lake decreased by ∼10%. DIC supply to the lake during this period, however, amounted to ∼10% of lake's inventory indicating that during 20 years, the lake lost ∼20% of its 1993s inventory. Compilation of historical data with our data shows that during the past two decades the lake's low DIC (∼1 mmol kg −1 ) and very high PCO2 (1800 ppm V) remained relatively constant, suggesting that a quasi-steady-state situation prevails. In spite of the surprisingly stable DIC and CO2 concentrations, during this 20 year period δ 13 CDIC increased significantly, from 1.4‰ to 2.7‰. An isotopic mass balance calculation together with the high PCO2 of the brine show that during that period the lake lost about 3.7 · 10 10 moles of DIC, of which ∼60% by CO2 degassing and ∼40% by aragonite precipitation. The deviation from the common 1:1 CO2 :CaCO3 ratio in most aqueous systems is facilitated by the dominance of the borate alkalinity of the Dead Sea. Nucleation and crystal growth experiments suggest that throughout this time the Dead Sea remained supersaturated with respect to aragonite, a situation facilitated by combination of slow nucleation rates and absence of growth surfaces. The very high PCO2 of the Dead Sea is maintained by the low CO2 piston velocity of the brine, calculated to be only ∼4.5 m yr −1, more than an order of magnitude slower than seawater value.