Effect of reprocessing cycles on the degradation of PP/PBAT-thermoplastic starch blends. (15th July 2017)

• Record Type: Journal Article
• Authors: Oliveira, Thainá A.; Oliveira, Rosimery R.; Barbosa, Renata; Azevedo, Joyce B.; Alves, Tatianny S.
• Is Part Of: Carbohydrate polymers. Volume 168(2017)
• Page Start: 52
• Page End: 60
• Publication Date: 2017-07-15
• Subjects: Recycling -- PP/PBAT-Thermoplastic starch -- Degradation; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2017.03.054
• Languages: English
• ISSNs: 0144-8617

Abstract

Highlights: Reprocessing of PP/PBAT-Termoplastic starch blend. Influence of PBAT-Termoplastic starch on reprocessing of PP. Degradation thermo-mechanical effects on the properties of PP/PBAT-Termoplastic starch blend. Abstract: The solid waste management problems caused by the accumulation of plastics require measures to mitigate the environmental damage, and mechanical recycling of plastics is among the possible solutions. In this context, the present study aimed to evaluate the effects of mechanical recycling on the properties of a polypropylene/poly(butylene adipate co-terephthalate)-thermoplastic starch blend (PP/PBAT-Thermoplastic starch blend) when it was subjected to seven reprocessing cycles by a single-screw extruder. The observations by infrared spectroscopy indicated that the chemical structures of the blend and the polypropylene matrix did not present significant changes with the reprocessing cycles. The X-ray diffraction analyses showed that the PP crystals were most affected when reprocessed in their pure form. The observations by thermogravimetry and differential scanning calorimetry indicated that the thermal stability of the blend was higher than that of polypropylene during the extrusion cycles. The scanning electron microscopy images indicated a weak interfacial interaction between the components of the blend, and the mechanical properties showed that the reprocessing improved the elasticity modulus and yield stress, with a consequential decrease of the impact strength.