Decoupling atomic-layer-deposition ultrafine RuO2 for high-efficiency and ultralong-life Li-O2 batteries. (April 2017)

• Record Type: Journal Article
• Authors: Zhao, Changtai; Yu, Chang; Banis, Mohammad Norouzi; Sun, Qian; Zhang, Mengdi; Li, Xia; Liu, Yulong; Zhao, Yang; Huang, Huawei; Li, Shaofeng; Han, Xiaotong; Xiao, Biwei; Song, Zhongxin; Li, Ruying; Qiu, Jieshan; Sun, Xueliang
• Is Part Of: Nano energy. Volume 34(2017:Apr.)
• Page Start: 399
• Page End: 407
• Publication Date: 2017-04
• Subjects: Li-O2 batteries -- RuO2 -- Atomic layer deposition -- Long cycle life -- High temperature; Nanoscience -- Periodicals; Nanotechnology -- Periodicals; Nanostructured materials -- Periodicals; Power resources -- Technological innovations -- Periodicals; Nanoscience; Nanostructured materials; Nanotechnology; Power resources -- Technological innovations; Periodicals; 621.042
• DOI: 10.1016/j.nanoen.2017.02.030
• Languages: English
• ISSNs: 2211-2855

Abstract

Abstract: Li-O2 batteries with ultrahigh theoretical energy density have triggered worldwide research interests and hold the prospect for powering electric vehicles. However, the poor cycling stability and low energy efficiency of Li-O2 batteries still remain and hamper their practical application. Configuring desirable porous cathodes with uniformly dispersed and highly active catalysts is a noteworthy and feasible approach to overcoming these critical obstacles. Herein, we report on a novel strategy for the fabrication of Mn3 O4 nanowires and carbon nanotubes composite film (Mn3 O4 /CNTs film) with ultrafine RuO2 nanoparticles (Mn3 O4 /CNTs-RuO2 film), in which the Mn3 O4 /CNTs film was employed as a conductive and porous matrix and extremely low amount of RuO2 (just 2.84 wt%) are uniformly dispersed onto this matrix by using atomic layer deposition method, and reveal its electrochemical behaviors as a free-standing air electrode for Li-O2 batteries. The Mn3 O4 /CNTs-RuO2 film delivers a high specific capacity, improved round-trip energy efficiency and ultra-long cycle life (251 cycles). The superior electrochemical performance can be attributed to the enhanced catalytic activity of the grafted RuO2 with modulated electronic structure as the result of the interaction with substrate, which is evidenced by the corresponding X-ray absorption spectroscopy results and the unique nanosheet-shaped discharge product which can be smoothly decomposed. Graphical abstract: Highlights: An advanced atomic layer deposition strategy was developed to controllably synthesize RuO2 catalyst. The as-made catalysts just use 2.84 wt% RuO2 but deliver a superior cycle life over 1700 h. The grafted RuO2 with modulated electronic structure can confine chemical disproportionation reactions of LiO2 . The as-made catalyst enable the discharge product featuring the ultrathin nanosheet structure.