Preparation and Reactions of Perfluoroalkanesulfenyl Chlorides. Issue 4 (20th March 2017)

• Record Type: Journal Article
• Authors: Xu, Ze‐Feng; Jiang, Min; Liu, Jin‐Tao
• Is Part Of: Chinese journal of chemistry. Volume 35:Issue 4(2017)
• Page Start: 442
• Page End: 446
• Publication Date: 2017-03-20
• Subjects: perfluoroalkanesulfenyl chloride -- perfluoroalkanesulfenyl acid -- substitution -- disulfide -- addition; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/cjoc.201600933
• Languages: English
• ISSNs: 1001-604X

Abstract

Abstract : Several perfluoroalkanesulfenyl chlorides were prepared from the corresponding perfluoroalkanesulfenic acids in high yields, and their reactions with thiol, amine, arene and alkene were studied. A series of perfluoroalkyl‐containing disulfides, sulfonamides, aryl sulfides and α ‐chlorosulfides were synthesized under mild conditions. Abstract : Perfluoroalkanesulfenyl chlorides were prepared from the corresponding perfluoroalkanesulfenic acids and their reactions with thiol, amine, arene and alkene were demonstrated.