Dissipation rates of saisentong residues in fresh tobacco, tobacco powder and soil determined by high-performance liquid chromatography coupled with diode array detection. Issue 4 (16th March 2017)

• Record Type: Journal Article
• Authors: Li, Zhining; Li, Feifei; Wei, Yue; Fan, Yi; Ma, Yanni; Wang, Wei; Liu, Yuqing; Zhao, Tianzeng; Lu, Ping; Zhang, Yuping; Hu, Deyu
• Is Part Of: International journal of environmental analytical chemistry. Volume 97:Issue 4(2017)
• Page Start: 355
• Page End: 367
• Publication Date: 2017-03-16
• Subjects: High-performance liquid chromatography -- Saisentong -- Residue -- Dissipation -- Tobacco -- Soil; Ecology -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental chemistry -- Periodicals; Pollution -- Periodicals; 577.14
• DOI: 10.1080/03067319.2017.1315111
• Languages: English
• ISSNs: 0306-7319

Abstract

ABSTRACT: Two independent field trials were performed in Guizhou and Hunan, China in 2013 to investigate the dissipation and residue levels of saisentong in tobacco and soil. A novel and accurate method using high-performance liquid chromatography with diode array detection was developed and validated to determine saisentong levels in tobacco and soil. The average recovery of saisentong at fortification levels of 0.5, 2.5, 5.0 and 50.0 mg kg −1 in fresh tobacco ranged from 75.92 to 107.40% with a relative standard deviation (RSD) of 0.94 to 7.55%, that at fortification levels of 0.5, 2.0 and 5.0 mg kg −1 in tobacco powder ranged from 74.96 to 94.43% with a relative standard deviation (RSD) of 4.38 to 8.14%, and that at fortification levels of 0.1, 0.5 and 5.0 mg kg −1 in soil ranged from 86.90 to 100.0% with an RSD of 1.38 to 4.62%. The limit of detection (LOD) of saisentong was 0.15 mgkg −1 in tobacco and 0.03 mg kg −1 in soil, and the limit of quantification (LOQ) was 0.5 mg kg −1 in tobacco and 0.1 mg kg −1 in soil, respectively. For field experiments, the half-lives of saisentong in tobacco from Guizhou and Hunan were 5.9 and 1.6 days, respectively; those in soil were 14.7 and 12.0 days, respectively. The results suggest that the saisentong dissipation curves followed the first-order kinetic. The terminal residues of saisengtong in tobacco ranged from 0.5 to 9.39 mg kg −1 at pre-harvest intervals (PHI) of 7, 14 and 21 days.