Highly selective CO2vs. N2 adsorption in the cavity of a molecular coordination cage. Issue 31 (5th April 2017)
- Record Type:
- Journal Article
- Title:
- Highly selective CO2vs. N2 adsorption in the cavity of a molecular coordination cage. Issue 31 (5th April 2017)
- Main Title:
- Highly selective CO2vs. N2 adsorption in the cavity of a molecular coordination cage
- Authors:
- Wright, James S.
Metherell, Alexander J.
Cullen, William M.
Piper, Jerico R.
Dawson, Robert
Ward, Michael D. - Abstract:
- Abstract : A cubic coordination cage shows high selectivity for CO2 vs. N2 uptake in the cage cavity, despite the bulk material being non-porous. Abstract : Two M8 L12 cubic coordination cages, as desolvated crystalline powders, preferentially adsorb CO2 over N2 with ideal selectivity CO2 /N2 constants of 49 and 30 at 298 K. A binding site for CO2 is suggested by crystallographic location of CS2 within the cage cavity at an electropositive hydrogen-bond donor site, potentially explaining the high CO2 /N2 selectivity compared to other materials with this level of porosity.
- Is Part Of:
- Chemical communications. Volume 53:Issue 31(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 31(2017)
- Issue Display:
- Volume 53, Issue 31 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 31
- Issue Sort Value:
- 2017-0053-0031-0000
- Page Start:
- 4398
- Page End:
- 4401
- Publication Date:
- 2017-04-05
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc01959a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 367.xml