Site-selective benzoin-type cyclization of unsymmetrical dialdoses catalyzed by N-heterocyclic carbenes for divergent cyclitol synthesis. Issue 32 (5th April 2017)
- Record Type:
- Journal Article
- Title:
- Site-selective benzoin-type cyclization of unsymmetrical dialdoses catalyzed by N-heterocyclic carbenes for divergent cyclitol synthesis. Issue 32 (5th April 2017)
- Main Title:
- Site-selective benzoin-type cyclization of unsymmetrical dialdoses catalyzed by N-heterocyclic carbenes for divergent cyclitol synthesis
- Authors:
- Kang, Bubwoong
Wang, Yinli
Kuwano, Satoru
Yamaoka, Yousuke
Takasu, Kiyosei
Yamada, Ken-ichi - Abstract:
- Abstract : A highly site-selective NHC-catalyzed benzoin-type cyclization of unsymmetrical dialdoses was achieved. Abstract : A highly site-selective N-heterocyclic carbene (NHC)-catalyzed benzoin-type cyclization of unsymmetrical dialdoses is developed to enable a divergent cyclitol synthesis. The choice of chiral NHCs and protecting groups affects the site-selectivity. The resulting inososes are converted into epi -, muco - and myo -inositols, and their chiral protected derivatives are formed in good yields.
- Is Part Of:
- Chemical communications. Volume 53:Issue 32(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 32(2017)
- Issue Display:
- Volume 53, Issue 32 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 32
- Issue Sort Value:
- 2017-0053-0032-0000
- Page Start:
- 4469
- Page End:
- 4472
- Publication Date:
- 2017-04-05
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc01191a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2662.xml