Boosting Organic Photovoltaic Performance Over 11% Efficiency With Photoconductive Fullerene Interfacial Modifier. Issue 1 (4th January 2017)

• Record Type: Journal Article
• Authors: Huang, Jiang; Zhang, Xiaohua; Zheng, Ding; Yan, Kangrong; Li, Chang‐Zhi; Yu, Junsheng
• Is Part Of: Solar RRL. Volume 1:Issue 1(2017)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2017-01-04
• Subjects: Solar energy -- Periodicals; Photovoltaic power generation -- Periodicals; Solar energy -- Research -- Periodicals; Photovoltaic power generation -- Research -- Periodicals; Periodicals; 333.7923
• DOI: 10.1002/solr.201600008
• Languages: English
• ISSNs: 2367-198X

Abstract

Abstract : A interfacial modifier, [5, 6]‐open azafulleroid (OPCBM) is utilized to engineer the organics–metal oxide heterojunction of inverted organic photovoltaics (OPVs). Mechanistic studies disclose that the OPCBM treatment not only passivates the metal oxide surface defects, but also improves energetic alignment and conductivity of interlayer due to the excited charge transfer characteristics from azafulleroid to ZnOx . With the assistance of π‐orbital hybridization from fullerene to the beneath ZnOx (through anchoring group), the electronic coupling and charge transfer from organics to metal oxide are effectively enhanced through the mediation of OPCBM modifier. It enables the overall internal quantum efficiency (IQE) approaching 100% and fill factor of 0.77 for the PTB7‐Th:PC71 BM based inverted OPVs, with the best PCE as high as 11.3%. Abstract : An aza[60]fulleroid atop of metal oxide can boost organic photovoltaic performance over ∼11.3% efficiency and fill factor of 0.77. The fullerene modifier not only passivates ZnOx surface defects, but also improves energetic alignment and charge extraction of modified interlayer due to the excited charge transfer characteristics from azafulleroid to ZnOx .