Using Vinyl Acetate, N‐Hydroxymethyl Acrylamide, and Montmorillonite Intercalated by a Dioctadecyl Dimethyl Ammonium Bromide Surfactant to Prepare Exfoliated Nanocomposite through In Situ Polymerization. Issue 2 (21st September 2015)

• Record Type: Journal Article
• Authors: Cui, Hui‐Wang; Fang, Qun; Du, Guan‐Ben
• Is Part Of: Advances in polymer technology. Volume 36:Issue 2(2017)
• Page Start: 211
• Page End: 219
• Publication Date: 2015-09-21
• Subjects: Mechanical properties -- Nanocomposites -- Nanolayers -- Rheology -- Microstructure; Plastics -- Periodicals; Polymers -- Periodicals; 668.9
• DOI: 10.1002/adv.21601
• Languages: English
• ISSNs: 0730-6679

Abstract

ABSTRACT: In this study, vinyl acetate, N ‐hydroxymethyl acrylamide (NMA), and organic montmorillonite intercalated by a dioctadecyl dimethyl ammonium bromide surfactant (MMT‐DOAB) were used to prepare exfoliated nanocomposites through in situ polymerization. Wide‐angle X‐ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy, power‐law function equation, Newtonian fluid flow equation, Cross–Williamson model viscous equation, Hooke's law, and Poisson's ratio equation revealed the structures, dispersion, rheology, and static tensile properties. The exfoliated nanocomposites were pseudoplastic non‐Newtonian fluids with good dispersion in water, great storage stability, and high static tensile strength at 6.89–8.15 MPa. The contents of NMA and MMT‐DOAB increased with the changes in synthesis precursors, as the calculated molecular weights did.