Enantioselective Barbier-type allylation of ketones using allyl halide and indium in water. Issue 25 (9th March 2017)
- Record Type:
- Journal Article
- Title:
- Enantioselective Barbier-type allylation of ketones using allyl halide and indium in water. Issue 25 (9th March 2017)
- Main Title:
- Enantioselective Barbier-type allylation of ketones using allyl halide and indium in water
- Authors:
- Nakamura, Shuichi
Hara, Yoshichika
Furukawa, Takashi
Hirashita, Tsunehisa - Abstract:
- Abstract : We disclose herein an efficient enantioselective Barbier-type allylation of ketones using allyl halide and indium metal in water. Abstract : We disclose herein an efficient enantioselective Barbier-type allylation of ketones using allyl halide and indium metal in water. The reaction was catalysed by chiral bis(imidazoline) to afford homoallylic alcohols having quaternary stereocenters in good yield with moderate to good enantioselectivity. Based on experimental investigation, a possible transition state has been proposed to explain the origin of the asymmetric induction.
- Is Part Of:
- RSC advances. Volume 7:Issue 25(2017)
- Journal:
- RSC advances
- Issue:
- Volume 7:Issue 25(2017)
- Issue Display:
- Volume 7, Issue 25 (2017)
- Year:
- 2017
- Volume:
- 7
- Issue:
- 25
- Issue Sort Value:
- 2017-0007-0025-0000
- Page Start:
- 15582
- Page End:
- 15585
- Publication Date:
- 2017-03-09
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/RA ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7ra01038a ↗
- Languages:
- English
- ISSNs:
- 2046-2069
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8036.750300
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 660.xml