A novel naphthalenediimide-based lanthanide–organic framework with polyoxometalate templates exhibiting reversible photochromism. Issue 15 (20th March 2017)

• Record Type: Journal Article
• Authors: Zhang, Hai-Long; Liao, Jian-Zhen; Yang, Wenbin; Wu, Xiao-Yuan; Lu, Can-Zhong
• Is Part Of: Dalton transactions. Volume 46:Issue 15(2017)
• Page Start: 4898
• Page End: 4901
• Publication Date: 2017-03-20
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt00631d
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The first visible-light-responsive photochromic polyoxometalate-templated lanthanide–organic framework (LOF) has been constructed from a carboxyphenyl-substituted naphthalenediimide (NDI) derivative. Abstract : The first visible-light-responsive photochromic polyoxometalate-templated lanthanide–organic framework (LOF) has been constructed from a carboxyphenyl-substituted naphthalenediimide (NDI) derivative, which displays an unusual four-fold interpenetration of an srs topological network, featuring a variety of anion–π interactions between polyoxoanions and π-acidic NDI moieties, and undergoes a rapid reversible photochromic transformation upon blue light irradiation.