Highly efficient cold-white light emission in a [Au2CuCl2(P∩N)2]PF6 type salt. Issue 11 (17th February 2017)

• Record Type: Journal Article
• Authors: Hobbollahi, Elnaz; List, Manuela; Hupp, Benjamin; Mohr, Fabian; Berger, Raphael J. F.; Steffen, Andreas; Monkowius, Uwe
• Is Part Of: Dalton transactions. Volume 46:Issue 11(2017)
• Page Start: 3438
• Page End: 3442
• Publication Date: 2017-02-17
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c7dt00180k
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The metallophilic interactions in the cluster [Au2 CuCl2 (P∩N)2 ]PF6 give rise to very efficient cold-white light emission. Abstract : In the trinuclear, heterometallic cluster compound [Au2 CuCl2 (P∩N)2 ]PF6 metallophilic interactions give rise to very efficient cold-white light emission as a result of at least two thermally non-equilibrated emissive triplet states (one of mainly Cu → py and the other of Au → py character, respectively) with exceptional spin–orbit coupling and short emission lifetimes, which are competitive to Pt II - and Ir III -based emitters.