Valence engineering of ionic molecular crystals: monovalent–divalent phase diagram for biferrocene–tetracyanoquinodimethane salts. Issue 11 (24th February 2017)

• Record Type: Journal Article
• Authors: Mochida, Tomoyuki; Funasako, Yusuke; Akasaka, Takahiro; Uruichi, Mikio; Mori, Hatsumi
• Is Part Of: CrystEngComm. Volume 19:Issue 11(2017)
• Page Start: 1449
• Page End: 1453
• Publication Date: 2017-02-24
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c7ce00134g
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : Ionic molecular solids composed of biferrocene derivatives (D) and tetracyanoquinodimethane derivatives (A) produce either divalent salts ([D] 2+ [A2 ] 2− ) or monovalent salts ([D] + [A2 ] − ) depending on the redox potential and molecular volume of the components. Abstract : The valence state of ionic molecular solids composed of biferrocene derivatives (D) and tetracyanoquinodimethane (TCNQ) derivatives (A), either monovalent ([D] + [A2 ] − ) or divalent ([D] 2+ [A2 ] 2− ), can be controlled by changing the redox potentials and molecular volumes of the components.