A solvent-free dense energetic metal–organic framework (EMOF): to improve stability and energetic performance via in situ microcalorimetry. Issue 21 (27th February 2017)

• Record Type: Journal Article
• Authors: Zhang, Yinli; Zhang, Sheng; Sun, Lin; Yang, Qi; Han, Jing; Wei, Qing; Xie, Gang; Chen, Sanping; Gao, Shengli
• Is Part Of: Chemical communications. Volume 53:Issue 21(2017)
• Page Start: 3034
• Page End: 3037
• Publication Date: 2017-02-27
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c7cc00545h
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : An interpenetrating EMOF without solvent molecules, which possess high stability and outstanding energetic properties, was obtained. Abstract : It is a tremendous challenge to prepare solvent-free dense energetic metal–organic frameworks (EMOFs), hence also to improve their stability and energetic performance. In this study, based on in situ microcalorimetry, an interpenetrating EMOF without solvent molecules, [Cu(tztr)] n (1, H2 tztr = 3-(tetrazol-5-yl)triazole) was obtained, possessing high stability ( T dec = 360 °C) and outstanding energetic properties (Δ H det = 7.53 kcal cm −3, D = 8.429 km s −1, P = 40.02 GPa).