Iron catalyzed efficient synthesis of poly-functional primary amines via the direct use of ammonia. Issue 19 (20th February 2017)
- Record Type:
- Journal Article
- Title:
- Iron catalyzed efficient synthesis of poly-functional primary amines via the direct use of ammonia. Issue 19 (20th February 2017)
- Main Title:
- Iron catalyzed efficient synthesis of poly-functional primary amines via the direct use of ammonia
- Authors:
- Ma, Chaoqun
Chen, Jianghui
Xing, Dong
Sheng, Yuan
Hu, Wenhao - Abstract:
- Abstract : An iron catalyzed three-component reaction of alkyl diazoesters, isatins and ammonia is reported. Abstract : An iron catalyzed three-component reaction of alkyl diazoesters, isatins and ammonia is reported. This reaction provided convenient access to non-protected β-hydroxy-α-aminoesters with adjacent quaternary stereocenters. This transformation is achieved via trapping of ammonium ylide which is generated from a diazocompound and ammonia under mild reaction conditions. Poly-functional group unprotected amines are obtained exclusively with up to 77% yield and 62 : 38 dr.
- Is Part Of:
- Chemical communications. Volume 53:Issue 19(2017)
- Journal:
- Chemical communications
- Issue:
- Volume 53:Issue 19(2017)
- Issue Display:
- Volume 53, Issue 19 (2017)
- Year:
- 2017
- Volume:
- 53
- Issue:
- 19
- Issue Sort Value:
- 2017-0053-0019-0000
- Page Start:
- 2854
- Page End:
- 2857
- Publication Date:
- 2017-02-20
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c7cc00003k ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1180.xml