Reactive insights into the selective dehydrogenation of ethylene diamine bisborane facilitated by phosphonium based Ionic Liquids. (2nd February 2017)

• Record Type: Journal Article
• Authors: Kundu, Debashis; Banerjee, Basudhrity; Pugazhenthi, G.; Banerjee, Tamal
• Is Part Of: International journal of hydrogen energy. Volume 42:Number 5(2017)
• Page Start: 2756
• Page End: 2770
• Publication Date: 2017-02-02
• Subjects: Ionic Liquid -- COSMO-SAC -- EDAB -- Phosphonium cation; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2016.09.215
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: The thermal dehydrogenation of ethylene diamine bisborane(EDAB) was performed on the COSMO-SAC screened Ionic Liquids namely Trihexyl(tetradecyl)phosphonium bis (2, 4, 4-trimethylpentyl) phosphinate and Trihexyl(tetradecyl)phosphonium dicyanamide. Dehydrogenation experiments were carried out under vacuum and temperatures of 95 and 105 °C. A maximum yield of 3.25 equivalents of hydrogen was obtained with EDAB/[TDTHP][Phosph] at 105 °C. 1 H NMR study confirmed the catalytic role of ILs during dehydrogenation. Further HR-MS analysis of residual products revealed the exact mass of end products. These were corroborated with the formation of oligomeric dehydrogenated EDAB compounds having four and five repeat units which eventually led us in formulating the reaction mechanism. Graphical abstract: Highlights: COSMO-SAC screening on 14 phosphonium based Ionic Liquids for EDAB dehydrogenation. Thermal dehydrogenation of EDAB with Trihexyl(tetradecyl)phosphphonium phosphinate and dicyanamide Ionic Liquids. Dual characterization with NMR and HR-MS spectra. Formulation of reaction mechanism for hydrogen release.